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Sepharite ram shouldn't affect your sync at all, try getting mplayer, I think there is a windows version of it now, or BSPlayer is a good one for windows, other players just have too much bloat.
The difference between xvid and divx is that xvid is free-software (open source) and has a better encodingtime/quality ratio than any other codec out there, and I think it's been rated second best for quality, there was some weird codec that gave better quality, but the time it took to encode wasn't worth it.
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