Adobe's Illustrator -->
http://www.adobe.com/products/illustrator/
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Adobe® Illustrator® CS2 software gives you new creative freedom that lets you realize your ideas quickly and powerfully. Instantly convert bitmaps to vector artwork and paint more intuitively. Save time with intelligent palettes and optimized workspaces. Plus, tight integration with other software allows you to produce extraordinary graphics for print, video, the web, and mobile devices.
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Basicly it lets you paint pictures you scan/draw on computer. You can do it with Photoshop, but this program is speciallized for your exact need. But sorry, I've never used it. Altohugh I hear its good.